Researchers develop solar cell that keeps working after sunset

About 750 million people in the world do not have access to electricity at night. Solar cells provide power during the day, but saving energy for later use requires substantial battery storage.

In a paper published in Applied Physics Letters, researchers from Stanford University have presented a photovoltaic cell that harvests energy from the environment during the day and night, avoiding the need for batteries altogether. The device makes use of the heat leaking from Earth back into space — energy that is in the same order of magnitude as incoming solar radiation.

At night, solar cells radiate and lose heat to the sky, reaching temperatures a few degrees below the ambient air. The device under development uses a thermoelectric module to generate voltage and current from the temperature gradient between the cell and the air. This process depends on the thermal design of the system, which includes a hot side and a cold side.

“You want the thermoelectric to have very good contact with both the cold side, which is the solar cell, and the hot side, which is the ambient environment,” said author Sid Assawaworrarit. “If you don’t have that, you’re not going to get much power out of it.”

The team demonstrated power generation in their device during the day, when it runs in reverse and contributes additional power to the conventional solar cell, and at night. The setup is inexpensive and in principle could be incorporated within existing solar cells. And because of its simplicity, construction in remote locations with limited resources is feasible.

“What we managed to do here is build the whole thing from off-the-shelf components, achieving a very good thermal contact, and the most expensive thing in the whole set-up was the thermoelectric itself,” said author Zunaid Omair.

Using electricity at night for lighting requires a few watts of power. The current device generates 50 mW per square metre, which means lighting would require about 20 m² of photovoltaic area.

“None of these components were specifically engineered for this purpose,” said author Shanhui Fan. “So I think there’s room for improvement, in the sense that, if one really engineered each of these components for our purpose, I think the performance could be better.”

The device generates electricity at night from the temperature difference between the solar cell and its surroundings. Source: Sid Assawaworrarit.

The team aims to optimise the thermal insulation and thermoelectric components of the device. They are exploring engineering improvements to the solar cell itself to enhance the radiative cooling performance without influencing its solar energy harvesting capability.

^{Assawaworrarit S, Omair Z and Fan S 2022, ‘Nighttime electric power generation at a density of 50 mW/m2 via radiative cooling of a photovoltaic cell’, Applied Physics Letters, vol 120, DOI: 10.1063/5.0085205.}

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